Is it reasonable to consider Ps as a chemical element?
It is bound electronically. If we consider atoms as having orbital
electrons, then the positron plays the role of nucleus.
It has a rich chemistry, as Google searches on "positronium halides,"
"positronium compounds," and other strings show. There are international
conferences on positronium chemistry.
In other exotic atoms such as muonium, pionium, and kaonium, the bound
muon or meson plays the role of an orbital electron instead of being the
nucleus. Although e−π+ and other such
atoms might equally well be regarded as elements, as would atoms with
hypernuclei, these contain unstable particles.
An isolated positron is presumably as stable as an electron.
One serious objection is that the positronium "nucleus" has non-zero
lepton number.
(e−π+ and atoms with hypernuclei have nuclei with lepton number
zero, as do "normal" nuclei.)